Detecting, characterising and assessing PEEK’s and CF-PEEK’s thermal degradation in rapid high-temperature processing
نویسندگان
چکیده
• A new fluorenone peak is detected at 1711 cm -1 that directly linked with the progress of thermal degradation in PEEK and CF-PEEK. Its intensity can be used to detect characterise extent rapid high-temperature processing It consists a useful tool for defining PEEK's CF-PEEK's optimum process window processing. 1% materials’ content found tolerable does not significantly affect degree crystallinity. Faster heating rates lesser crystallinity content. In this study, methodology proposed identify takes place Initially, their decomposition mechanisms are examined air thermogravimetric analysis (TGA). Then, CF-PEEK samples heated static conditions up temperatures close above onset 100 °C/min. The then attenuated total reflection - Fourier transform infrared (ATR-FTIR) spectroscopy degradation. correlation between its resulting it shown safely as characterising conditions. Finally, an investigation differential scanning calorimetry (DSC) conducted would induce severe damage on two materials. both CF-PEEK, faster have reduced effect around matrix tolerable.
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ژورنال
عنوان ژورنال: Polymer Degradation and Stability
سال: 2022
ISSN: ['1873-2321', '0141-3910']
DOI: https://doi.org/10.1016/j.polymdegradstab.2022.110096